![]() The chemical symbols identify the types of atoms. For example, the chemical formula for isopropyl alcohol is C 3H 8O. A chemical formula identifies the type and number of atoms that make up a molecule. Two of the most common are chemical and structural formulas. There are many ways to represent molecules. Some people define the smallest unit of sodium chloride as the sodium chloride compound, but a compound is a substance, not a cluster of atoms. Maybe that is okay since those smallest units are not permanent and constantly in flux, but it is inconvenient. However, sodium chloride, and any other pure substance formed by ionic or metallic bonds, does not have a name for its smallest unit. For water, and any other pure substance formed by covalent bonds, the smallest unit of the substance is a molecule. Sodium chloride (NaCl) is also a compound because it is a pure substance that consists of sodium and chlorine atoms. Water (H 2O) is a compound because it is a pure substance that consists of hydrogen and oxygen atoms. However, the oxygen atom is not the smallest unit of diatomic oxygen gas or ozone… the O 2 and O 3 molecules are, and all three of those pure substances have very different characteristic properties.Ī pure substance is classified as a compound when it consists of two or more different types of atoms (or elements). Oxygen atoms (O), diatomic oxygen gas (O 2), and ozone (O 3) are all elements since they consist only of oxygen atoms. Some textbooks define an atom as the smallest unit of an element, but that is not accurate. A pure substance is classified as an element when it consists of a single type of atom. Pure substances can typically be classified as either elements or compounds. Ionic bonds are chemical bonds because they form new substances intermolecular bonds do not. Sodium chloride is a completely different substance. Sodium is a soft, silvery metal that reacts violently in water (think explosions and poisonous gases) and chlorine is a yellow-green gas that acts as a strong bleach. And sodium chloride does not behave anything like sodium or chlorine. However, sodium chloride has a specific chemical composition (one sodium ion for each chlorine ion) and its own distinct characteristic properties, such as density, boiling and melting points, and heats of vaporization and fusion, something that mixtures do not have. We could say that ionic bonds are not chemical bonds at all, but intermolecular bonds… and that sodium chloride is a mixture and not a pure substance. ![]() That is why a water molecule is a molecule and a sodium chloride ion pair is not. The oxygen atom in a water molecule is paired with two specific hydrogen atoms, and those pairs do not change until a chemical reaction breaks the molecule apart. Unlike ionic bonds, covalent bonds cannot be broken without creating new molecules and substances. ![]() Two atoms that form a covalent bond are physically sharing electrons. While the hydrogen and oxygen atoms in a water molecule are also held together by electrostatic attraction, they also have overlapping orbitals. ![]()
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![]() So I like totally respect this book for pioneering a new sub genre I like to call: “2000’s Gothic”. And yet it still weaves comedy masterfully into the plot without breaking the tension of the mind games and hostile environment like ever!!!!!! And not to mention it makes like the diary of a middle schooler high art!! I’m so freaking over this master piece! OMG GUYS!! This is like so totally the most thrilling psychological gothic, uhm, Thriller you guys have ever seen. This is a series that is a must read for younger girls and anybody that like reading fun contemporary middle grade books. I wish there were moments of Nikki and Brandon in this one. I didn't love this one quite as much as the others, but this one was still pretty great. As I've mentioned in some of my other reviews, I would love to see a spin-off series just focused on them. I love to read the little snippets that Briana, Nikki's sister, and Miss Penelope, a drawn-on face on Briana's hand. I've read enjoyed all of the books in this series. Will Nikki be able to get closer to Brandon and prevent Mackenzie from turning Brandon in for a prank that was her fault? Nikki winds up off the sign-up list, but gets her the opportunity to write an anonymous advice column as Miss Know it All. The only solution Nikki can come up with is to join the newspaper to prevent Mackenzie from turning in Brandon for the prank. Mackenzie threatens Nikki that she better get her and her friend invited. Mackenzie is furious when she isn't invited to Brandon's party but Nikki and her friends are invited. ![]() Nikki and her friends can't believe they are getting away with it. However, Mackenzie is convinced that Brandon, Nikki's crush, did it because he's crushing at her. They all go and toilet paper her house, and Mackenzie catches them before they can leave. At first, she doesn't want to, but then thinks about all the mean things that Mackenzie has done to her and her friends. She is dared to toilet paper Mackenzie Hollister house, a CCP girl that she can't stand. They play truth or dare, and to avoid answering questions about Brandon, Nikki chooses a dare. Nikki is at a sleepover with her friends Chloe, and Zoey. It was amazing, and the illustrations were hilarious. ![]() Will she get the present? Can she keep up with the advice letters? Read to find out! I recommend this book to any tween girl. The party is getting closer and she still doesn't have a present. She goes to the mall, but spends all her money on her sister and her self. Nikki needs to find Brandon, her crush a birthday present. But in the end there are over two hundred notes a day. The first day of checking the advice boxes the only thing that was in them was trash. This is the advice column of the newspaper. ![]() Eventually he gives her the job of Miss-Know-it-All. Mr.Zimmerman won't talk to Nikki about this. ![]() Mackenzie is off to her tricks again though, she scribbled Nikki's name off the sign up sheet. To make sure Mackenzie doesn't put any thing in the newspaper she joins the school newspaper team. Her dad started working for Mackenzie's dad and might work full time. Another reason she might have to leave is because she attends the school on a bug extermination scholarship. Mackenzie threatened to tell the principal and get Chloe, Zoey, and Nikki thrown out of school. Nikki toilet papered Mackenzie's house because Mackenzie is a witch. She is in danger of having to leave the school again. ![]() ![]() Juventus: Final score 3, ronaldo bicycle kick vs juventus HD wallpaper
![]() ![]() If Time Trial appears to be grayed out, the game has registered that there are two players and you’ll know you’ve entered split-screen mode. You’ll each get a message letting you know that the other player has joined the game.From the DIRT 5 menu, all players must hit the touchpad on the controller at the same time.Heads-up that you’ll need at least two player accounts created on your console and a controller assigned to each player. Make sure the console is picking up both controllers and that the PlayStation symbol light is lit for both players.Split-screen won’t work on PlayStation 5 unless every player’s console is online and every player completes the first tutorial race.Each player must complete the first tutorial race.Make sure you have two-player mode enabled. Choose Freeplay and adjust the settings how you like.You’ll each get a message letting you know that the second player is now in the game with you.Choose the gamertag (which must be different from player one).From the DIRT 5 menu, the second player needs to press and hold the View button.Heads-up that you’ll need at least two users (gamertags) created on your console and a controller assigned to each gamertag. Series S and X users may have to plug the second controller into the front USB port. Make sure the console is picking up both controllers and that the Xbox symbol light is lit for both players.To get started in your split-screen adventures, make sure all players are logged in to an online account and have your controllers switched on. Check out the steps to get split-screen working. The cloud backups are great and will generally suffice, but there can be some strange glitches that can arise from couch co-op and it would be nice to limit the damage to a few sessions instead of an entire season.DIRT 5 lets up to four friends race together in split-screen mode. The main advice I'd offer is that you get into the habit of regularly backing your save games up onto a USB stick. Then, maybe, decide whether to continue seasonal in the future or to switch it up. Work through the seasonal journey (at least the first four chapters, but ideally all the way to the end) and then after the season your seasonal characters will naturally become non-seasonal. Since you're already running seasonal and already leveled up and ready to approach the end-game, I'd suggest you stick with it for now. And it rewards you quite nicely, with exclusive cosmetics and a full set of green gear to wear. Meanwhile, seasonal offers the excellent Seasonal Journey questline that will guide you through all the end-game concepts you need to know - including getting the cube and using it. Sharing loot is great, but TBH the game gives you so much loot that you won't struggle all that long in trying to find what you need with or without sharing. It's never too late to go get the cube, for example. There isn't much you can do to legit screw up your characters or progression. As soon as the grind becomes boring, find a guide and try something new. Of all games, this is the one we keep coming back to. ![]() The cube helps with a lot of stuff, such as uppgrading rares and made the grind a lot better. With the armory it's easy to have different sets saved there without needing to start a new toon. Gears of dredland is also a great set if you want speed for farming, not as strong, but very fast in the beginning. Monk is most powerful now, but is much harder to master. This season I would recommend the Marauder set for Demon Hunter, it's great for beginners and gets fairly strong. Offline is fun, to share stuff, but seasonal play is our thing now when we have done the story many times and found all pets and stuff. The fun part is goblinhunting for pets and rare wings, and finding sets and learning how they work. Now the game "starts" at lv 70 and we just rush that bit every season. My gf and I also plays on PS5, but we have played Diablo 3 since PS3. ![]() ![]() ![]() ![]() ![]() Hi-Tec TRANS is recommended for many heavy duty transmissions and drives in a wide range of automotive, mining, agricultural and earthmoving applications and particularly: Long term rust and corrosion protection to steel and copperbased metal is assured by the inhibitors in Hi-Tec TRANS. The foam inhibitors in Hi-Tec TRANS provide effective protection against foam development thus avoiding metal-to-metal contact and further minimising wear.ĬORROSION PROTECTION. 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Marine Hi-Tec Oils Four-stroke Oil range is designed to achieve high performance combined with the latest developments in oil formulation and additive technology to deliver the best results and protection for your engine. ![]() ![]() See details Located in: Ewa Beach, Hawaii, United States Small (Under 24 in.) Baehr 32.75'' Tall 1 - Door Accent Cabinet by Zipcode Design™ From $123.99 $159.99 ( 17) Free shipping Sale Rigdel 42.5'' Tall 2 - Door Accent Cabinet by Red Barrel Studio® $129.99 $139.99 ( 13) Free shipping Sale +5 Colors Small (Under 24 in.) Argonaut 46.75'' Tall 3 - Door Accent Cabinet by Ebern Designs From $103.99 ( 474) Small Bathroom Storage Cabinet Floor Standing Toilet Paper Organizer W/ Shelves Condition: New Color Size Quantity: Last One Price: US $62.80 Buy It Now Add to cart Add to Watchlist Fast and reliable.At 26'' wide, this piece fits just right in small- to medium-size bathrooms.25malx 4364 1 cat code Two cabinet doors feature slatted details and six panes of rain-patterned textured glass for a coastal touch. A molded top rests on a clean-lined body that houses three interior shelves that provide ample storage for your towels, shampoos, and bathroom accessories. At 26'' wide, this piece fits just right in small- to medium-size bathrooms. Apr 8 Enneke Freestanding Bathroom Cabinet A molded top rests on a clean-lined body that houses three interior shelves that provide ample storage for your towels, shampoos, and bathroom accessories. We noticed more damage when retailers displayed other items on the tabletops and where there was more foot traffic (such as at West Elm).Small bathroom cabinets Dexter Freestanding Bathroom Cabinet by Red Barrel Studio® $61.99 $89.99 ( 50) Free shipping Sale Steinway Freestanding Bathroom Cabinet by Highland Dunes $53.99 ( 75) Free shipping Sale Freestanding Bathroom Cabinet by The Twillery Co.® $139.99 $219.99 ( 92) 2-Day Delivery FREE Shipping Get it by Sat. We found few tables with no damage at all. In general, almost all of the tables had some damage to their tabletops and to the bottoms of their legs (where a chair would typically hit the side of the table). Signs of wear: We looked for nicks and scratches on the surfaces of the floor-model tables as an indication of how they would perform under serious use in the home.We found that the smaller the apron (the framing that connects the tabletop to the legs), the more clearance we had to cross our legs and move around. We wanted to make sure that we could sit easily and comfortably and cross our legs underneath each table. Comfort: We sat at each table to determine its comfort.(All of the tables within our sub-$1,000 budget were held together with hardware, versus the traditional tongue-and-groove wood construction you might find in models at higher prices.) Stability and construction: We tried to shake, lift, and move the tables to gauge their quality.Many seemed bigger and darker than they did online-something to consider if you’re decorating a smaller space. Looks: We judged the tables for their overall appearance and compared with how they looked online.One person was able to put it together in around 15 minutes. We found the Damen easy to assemble-we just needed to attach the legs. You could tone down the country-kitchen look by using more-modern chairs or, down the line, painting the table it also comes in an unpainted version. The narrow, widely spaced legs offer maximum seating capacity. ![]() The piece’s small scale helps it work well for an apartment, as a kitchen table, or even as a desk or craft table. ![]() The oak tabletop on this model should be more durable than the pine that IKEA uses on its solid-wood tables (although it will still dent and scratch easily). The price includes delivery (through Amazon Prime), making it a good alternative if you want an inexpensive wood table and don’t live near an IKEA store (or have a car to get there). Despite being one of the cheapest solid-wood tables we’ve found, it’s well made and sturdy, with a varnished solid-wood top that feels like it will last. Why it’s great: The butcher-block-style Coaster Home Furnishings Damen Dining Table is one of Amazon’s best sellers and has high customer reviews. ![]() ![]() ![]() It’s possible to get around most of these shortcomings with the use of intermediary apps, but this approach may require extra learning time and costs. somewhat limited support for different types of hardware and a lack of availability of Lightspeed’s in-house payment processor in some countries, which means that you’ll have to use a third-party service). These include few native integrations for most well-known ecommerce platforms like Shopify, WooCommerce, BigCommerce etc. There are a handful of downsides and caveats that sellers should be aware of, however. Lightspeed also offers dedicated solutions for restaurants and golf clubs, each with an array of specialised tools. It has more or less everything you would expect from a point-of-sale system for brick-and-mortar retailers, including sales and customer management, sales histories, analytics, and intuitive back-office and front-end dashboards. Lightspeed scored reasonably well in the features category. If you decide to use Square’s in-house ecommerce solution, you will also have access to a user-friendly store builder, automated inventory syncing, and integration with Instagram.įinally, analytics reports cover sales, profit margins, vendor sales, and total costs. ![]() Tools include unlimited products, low stock alerts, bulk inventory uploads, barcode printing, and more. ![]() You won’t find anything lacking on the inventory management front, either. Payment functionality, which works on a straightforward, transparent fee structure, comprises next-day transfers, invoices, and both physical and digital gift cards. Support for Android tablets is not provided, but you can download a feature-limited Android app to take mobile payments.Ĭheckout features include saved carts, barcode scanning via the iPad camera or Square register, discounts, item searches, and exchanges. The register interface is accessed via an iPad or the Square register. Square back-office is a browser-based app. The free plan provides only limited functionality. Keep in mind that you will only have access to all features on the $60/month “Plus” package. Square for Retail has a fairly comprehensive feature-set and comes with everything you would expect from a point-of-sale system. There is also the option to integrate with Square’s ecommerce platform if you don’t already have an online store. On the negative side, we would have liked to have seen more third-party integrations, cheaper hardware (many competitor plans include a free card reader), and deeper levels of functionality in some areas.Īll in all, however, Square offers an inexpensive and easy-to-use system for small and medium retailers that don’t want the hassle of having to navigate a more complex app. If you run a larger store, with sales above $250,000 annually, you qualify for a custom pricing package. This is very competitive when compared to other processors, although you will pay slightly more on the free plan. If you’re not on the free plan, you will pay $60 for each location (with unlimited staff numbers and permissions) and a transaction fee of 2.5% plus ten cents. Square’s fee structure is also relatively straightforward. Notably, Square offers what is perhaps one of the best free plans on the market, although users will have to pay for hardware and the ability to add additional team members at $35 per location. Square for Retail has everything you would expect from a point of sale system, including built-in payment processing, integrations with ecommerce platforms, inventory management, a good (if slightly expensive) selection of hardware options, and a fairly comprehensive analytics dashboard. This review will focus on the retail option. It is offered alongside several other solutions, including Square for Restaurants and Square Appointments (for appointment-based service businesses). Square for Retail is Square’s dedicated point of sale system (POS) for brick-and-mortar retailers. ![]() ![]() ![]() Assessment of change in symptoms, such as via a symptom score, was not provided. Defining who was an “athlete” depended on documentation and adjudication. The retrospective design highlights some limitations and future areas of study. This potential side effect of ablation can be symptomatic and should be discussed with patients preprocedure. The elevated heart rate post-ablation usually resolves in most patients, but seems to be a persistent manifestation of autonomic modulation post-ablation in athletes. It supports consideration of early ablation in symptomatic athletes, especially at the paroxysmal stage. ![]() This is the largest and most detailed study to date of an athletic population undergoing catheter ablation for AF. In the eight patients with pre- and post-procedure ETTs, exercise capacity was essentially unchanged, although heart rate recovery at 1 minute was significantly reduced. Resting heart rate at 1 year was increased by approximately 10 bpm compared to preablation in the 39 patients with data available. Longer diagnosis-to-ablation time was associated with arrhythmia recurrence, and pulmonary vein isolation within 2 years of diagnosis was significantly associated with lower recurrence. Arrhythmia-free survival was similar between competitive and noncompetitive, endurance versus nonendurance athletes. Rate of arrhythmia recurrence was the same in the matched cohort of nonathletes left atrial (LA) diameters and volumes were also similar. Accounting for multiple procedures, success improved to 86%, 76%, and 56% in respective groups by the end of follow-up. Single-procedure success was 75%, 68%, and 33% at 1 year for paroxysmal, persistent, and long-standing persistent AF, respectively. The study cohort was comprised of 144 athletes (93% men mean age, 50 years 72% endurance sports 67% paroxysmal, 26% persistent, and 6% long-standing persistent AF). The athlete cohort was compared to a matched group of nonathletes from the original database. Resting heart rate was assessed by electrocardiograms (ECGs) in sinus rhythm pre- and post-procedure. All patients underwent evaluation for pulmonary stenosis 3-6 months post-procedure. Arrhythmia recurrence was defined as >30 seconds of atrial arrhythmia recorded after the usual 3-month post-ablation blanking period and procedure success was defined as freedom from antiarrhythmics. Diagnosis to ablation time was defined as time from initial AF diagnosis to ablation. Exercise treadmill tests (ETTs) had to be performed within 5 years of the ablation. Only first-time ablation patients were included, but the ablation approach was not limited to isolation of the pulmonary veins-additional lines were “typically” performed. Ablation was performed with the cryoballoon in two patients and radiofrequency ablation in the rest. Two of the exclusion criteria were age >65 years old and body mass index (BMI) >30 mg/m 2. An “athlete” was defined as someone: 1) competing in a structured training program, or 2) exercising frequently and vigorously (>6.0 METs). (subsidiary of Teleflex Inc.Athletes were identified from a single-center database of consecutive patients undergoing catheter ablation for AF over a 15-year period. Learn more about medical device recalls.Ģ Per FDA policy, recall cause determinations are subject to modification up to the point of termination of the recall.ģ For details about termination of a recall see Code of Federal Regulations (CFR) Title 21 §7.55.ĥ10(K)s with Product Code = FOZ and Original Applicant = Arrow Internation, Inc. The record is updated if the FDA identifies a violation and classifies the action as a recall, and it is updated for a final time when the recall is terminated. states: CO, FL, IL, NC, PA, SC, and TX.ġ A record in this database is created when a firm initiates a correction or removal action. ![]() If you have no affected stock, please complete the enclosed Recall Acknowledgment Form and fax it to Arrow.ĭistributed in the following U.S. To return product, complete the enclosed Recall Acknowledgement Form and fax it to Arrow.ģ. If you have affected stock, quarantine so that the affected products can beĢ. Notification letters were sent to consignees with the following instructions: 1. Class 2 Device Recall ARROW ENDURANCE" Extended Dwell Peripheral Catheter SystemĬatheter,intravascular,therapeutic,short-term less than 30 days - Product Code FOZĪRROW ENDURANCE" Extended Dwell Peripheral Catheter System, Catalog Numbers: EDC-00820 & EDC-00820-BĬatalog Number: EDC-00820, Lot: 14X17C0039 (Expires February 2019) Catalog Number: EDC-00820-B, Lot: 13F17F0120 (Expires May 2019)Ĭertain lots of peripheral catheter systems may be missing the safety latch, intended to minimize the risk of sharps injuries. ![]() ![]() ![]() ![]() When Chris Blackwell, founder of Island Records, sent the record to his contacts in the music industry, Eric Clapton heard something he liked and transformed "I Shot the Sheriff" into a No. "We were grown and raised in the ghetto, so we knew nothing more than a ghetto life," she says.īut Burnin' was also a breakthrough for Marley - and for reggae music's acceptance in the U.S. Rita Marley, his widow, sees the connection. Bob Marley and the Wailers (previously known as The Wailers, and prior to that The Wailing Rudeboys, The Wailing Wailers and The Teenagers) were a Jamaican ska, rocksteady and reggae band. Clapton’s cover significantly elevated Bob Marley’s international profile, the same year that Peter. The political stridency of Burnin' was informed by the slums where Marley lived. Featuring some of Bob’s most celebrated songs Burnin introduced their timeless anthem of insurgency Get Up Stand Up and I Shot The Sheriff, which Eric Clapton covered and took to the top of the Billboard Hot 100 in 1974. Burnin' covers a variety of topics and moods, from the militancy of "Get Up, Stand Up" and "I Shot the Sheriff" to the heartfelt rage and poverty-induced despair of "Burnin' and Lootin'." The final track, the traditional "Rastaman Chant," sounds a more redemptive note. While the band was rhythmically tight, Marley dominates this album. It turned out to be Bob Marley's big break.īurnin' was the last album the reggae master released under the name "The Wailers," and it featured the final performances of Peter Tosh and Bunny Wailer with the group. In 1973, a reggae group on the verge of breaking up released an album - its second that year - filled with militant anthems inspired by life in the Jamaican slums. Cornel Campbell - Sings Hits of Studio One and More 1997 Wherever I Lay My Hat Once in a Greenwich Farm My Dearest Darling I Love You Madly Girl of My Dreams Stars. The most famous reggae performer was Bob Marley, whose recordings featured. Hide caption View a Slideshow of the Interviewees toggle caption Stephen Marley, Wale, The Cast of Fela - Made In Africa Stephen Marley - False Friends Stephen Marley, Capleton - Break Us Apart Steph. Lucky Dube VS Bob Marley Songsĭrop your Comment And Share As You Download, Listen, Stream & Enjoy Strictly Bob Marley & Lucky Dube Mixtape Download The Best Of Bob Marley vs Lucky Dube Mix ( 89.Bob Marley performs at a 1978 concert in Sweden. Year 2022 DJ Mix Bob Marley & the Wailers, The Wailers and Lucky Dube. It is the fourth effort with the Wailers and the last one with the legendary original lineup featuring. But Burnin’, released in 1973, remains the most genuine definition of the roots reggae sound. Download The Best Of Bob Marley vs Lucky Dube Mix ( 89.73 Mb ) On every album that he made with the Wailers, Marley showed solidarity with his fellow countrymen and managed to allow reggae to evolve each time. ![]() ![]() Your card information is secure even from their own employees because the systems never display the full card numbers, even on administration screens. ![]() Their systems only allow access to our most senior staff and only in extenuating circumstances (such as investigations of Card Fraud by the Police). No individuals within our company or SagePay are able to decrypt transaction information or cardholder data. Any cardholder information sent to the banks and any authorisation message coming back is secure and cannot be tampered with. SagePay has multiple private links into the banking network that are completely separate from the Internet and which do not cross any publicly accessible networks. 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Internationally recognised encryption and data storage Antique Silver Octopus Decorative Bookends Set 5 Inch Tall (Set of 2). ![]() You can be completely secure in the knowledge that nothing passed to SagePay can be examined, used or modified by any third parties attempting to gain access to sensitive information. No cardholder information is ever passed unencrypted and all messages from SagePay are signed using MD5 hashing to prevent tampering. SagePay are used by thousands of other UK businesses for transaction security.Īll transaction information passed between our website and the SagePay Payment System is encrypted using 128-bit SSL certificates. We use SagePay which are an industry leader in secure internet transactions. Besides these two permanent showrooms, we exhibit regularly in New York City, Los Angeles, Denver, Las Vegas and Orlando.When you shop with us, our secure server encrypts all of your personal information, including name, address and credit card information. Our company participates in major trade shows all over the United States and have showrooms located in the two largest giftware market in the United States, Atlanta and Las Vegas. Buy Creative Co-Op Octopus Shaped Resin (Set of 2 Pieces) Bookends, Silver, 2: Decorative Bookends - FREE DELIVERY possible on eligible. Octopus Bookends, Ocean Life Decor, Metal Art, Book Ends. ![]() Since its humble beginning in 1982, Pacific Trading has been experiencing tremendous growth and rapid expansion of product lines made from various materials. Set of 2 Unique Funky Silver Resin Octopus Kraken Bookends Home Decor (4.9k) 119.99. Pacific Trading is a manufacturer and distributor of giftware, tabletop accessories, home décor accessories and dollhouse accessories headquartered in Edmond, Oklahoma. 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FUNCTIONAL AND DECORATIVE: Best for enhancing one's home or study room with its superb design that will surely bring good vibes to your area while keeping your books in place Read reviews and buy Resin Octopus Bookends - Silver - 3R Studios at Target. ![]() |
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